This was 11.4 percent lower than the state average of 41.8 percent. In 2020 the total municipality population reached 809.
86.9 percent of the population had at least a high school diploma or the equivalent.
Degree distribution in Pepin for 2020*
| Degree | Number of people | Percentage of population |
|---|---|---|
| No degree | 82 | 13.1 |
| Regular high school diploma | 216 | 34.6 |
| GED or alternative credential | 16 | 2.6 |
| Some college, less than 1 year | 30 | 4.8 |
| Some college, 1 or more years, no degree | 90 | 14.4 |
| Associate's degree | 73 | 11.7 |
| Bachelor's degree | 88 | 14.1 |
| Master's degree | 22 | 3.5 |
| Professional school degree | 4 | 0.6 |
| Doctorate degree | 3 | 0.5 |
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